Development of heat transfer and evaporation model of LNG covered by Hi-Ex foam

Natural gas is a kind of clean, efficient green energy source, which is used widely. Liquefied natural gas (LNG) is produced by cooling natural gas to −161 °C, at which it becomes the liquid. Once LNG was released, fire or explosion would happen when ignition source existed nearby. The high expansion foam (Hi-Ex foam) is believed to quickly blanket on the top of LNG spillage pool and warm the LNG vapor to lower the vapor cloud density at the ground level and raising vapor buoyancy. To identify the physical structure after it contacted with LN₂ and to develop heat transfer model, the small-scale field test with liquid nitrogen (LN₂) was designed. In experiment, three layers including frozen ice layer, frozen Hi-Ex layer and soft layer of Hi-Ex foam were observed at the steady state. By characterizing physical structure of the foam, formulas for calculating the surface of single foam bubble and counting foam film thickness were deduced. The micro heat transfer and evaporation model between cryogenic liquid and Hi-Ex foam was established. Indicating the physical structure of the frozen ice layer, there were a certain number of icicles below it. The heat transfer and evaporation mathematical model between the frozen ice layer and LNG was derived. Combining models above with the heat transfer between LNG, ground and cofferdam, the heat transfer and evaporation mathematical model of LNG covered by Hi-Ex foam was developed eventually. Finally, LN₂ evaporation rate calculated by this model was compared with the measured evaporation rate. The calculated results are 1.2–2.1 times of experimental results, which were acceptable in engineering and proved the model was reliable.     

Low uptakes of Cd,Cu, and Zn in Dugesia japonica,a freshwater planarian with higher tolerance to metals

Although a freshwater planarian is proposed as a potential model for studying toxicities of environmental pollutants, they are less sensitive to metal exposures, compared to other freshwater invertebrates. We hypothesised that the metal uptake is low in treated planarians, which may lead to their higher tolerance to metals. The acute toxicities of Cu and Zn to Dugesia japonica were determined. The 24- and 48-h median lethal concentrations were 4.50 and 3.46?mg?L^?1, respectively, for Cu, and 41.97 and 37.79?mg?L^?1, respectively, for Zn. Accordingly, combining with the data on Cd in our previous study, higher tolerance of planarians to metals was revealed. Also, tissue levels of Cd, Cu, and Zn in treated D. japonica were determined, and their dissolved uptake rate constants (k₁) were calculated. Results showed that bioaccumulations of these metals in D. japonica were, indeed, lower than that in other freshwater invertebrates having higher susceptibilities to these metals.     

不同种植方式对水生植物生长的影响

水生植物恢复是水体生态恢复与重建的一个关键,而人工快速大面积恢复沉水植物存在较大的难度。在淀山湖318国道近岸水域生态带内,运用水泥涵管覆土种植、箩筐覆土种植、纱布包裹覆土种植、编织袋覆土种植和竹签扦插法对水生植物进行种植。通过实验得出,运用水泥涵管覆土种植的芦苇存活率比用箩筐覆土种植的存活率高;运用水泥涵管覆土+竹签扦插法种植的狐尾藻存活率比其他几种种植方法的存活率高,几种种植方式下的生物量无显著差异。     

中国新克强指数的构建与实证分析

随着中国经济进入新常态,英国《经济学人》杂志构建的克强指数已无法反映中国经济的全貌,如何客观地反映中国经济的真实状况成为一个迫切需要解决的现实问题。为更好地测度中国经济运行的真实状况,本文根据李克强总理提出的"未来会更加关注就业、居民收入和生态环境的持续改善"的愿景,在原有克强指数的基础上,增加年末就业人员数、农村居民家庭人均纯收入、城镇居民家庭人均可支配收入等就业和收入方面的指标,使用中国1995—2015年的相关数据和层次分析法构建了克强指数的修订版本即新克强指数,并将新克强指数与GDP增长率、克强指数进行了比较,发现新克强指数在反映中国经济波动和经济整体运行状态上有更为优良的性质。与GDP增长率相比,新克强指数克服了服务业比重提高带来的熨平效应,进而灵敏地反映中国经济波动情况,并对异常事件更加具有敏感性。相对于克强指数而言,新克强指数破除了因中国在第二产业上存在失衡性发展所带来的经济波动的杠杆效应,降低了经济增长中的虚假成分,从而与中国经济运行的整体关联度更为密切。此外,相对于克强指数而言,新克强指数在反映经济景气方面有着较好的时效性与关联性。采用时差相关分析法对新克强指数与宏观经济指标之间的关系进行分析,发现新克强指数在反映第一产业增加值、第三产业增加值、最终消费支出、资本形成总额、对外贸易、通货膨胀等方面具有优势。研究表明:新克强指数是更适宜测度中国经济的多元评价指标,为测度中国经济运行的真实状况提供了科学的参考依据。     

过硫酸钾去除水中的TCE

以地水中的氯代烃污染物三氯乙烯(TCE)为目标污染物,以过硫酸钾溶液为氧化剂,探讨了不同条件下过硫酸钾对TCE的去除效果。实验结果表明,在40℃,过硫酸钾初始浓度为2.43 g/L条件下,反应2 h后,TCE的去除率就可达到96.8%;过硫酸钾对TCE的去除符合一级反应动力学方程,速率常数(K)为1.3364 h-1,半衰期(t1/2)为0.51 h;过硫酸钾对TCE的去除速率在pH为中性附近时最大,其后无论pH升高或降低去除速率均减小;受温度和pH影响较明显,并且反应温度越高,受pH的影响越明显;随离子强度的增加而减小;反应活化能为119.6 kJ/mol;过硫酸钾溶于水生成过硫酸根离子(S2O28-),S2O28-会进一步生成硫酸根自由基(SO4-.),在碱性条件下,SO4-.与OH-反应会进一步生成羟基自由基(.OH)。过硫酸钾对于TCE的去除主要源自SO4-.和.OH的强氧化性。     

复合沸石滤床修复北方景观水体的实验研究

以天然矿物质沸石、细砂及煤渣取代传统滤料构建复合基质生态床，表面种植景观植物，采用下向流-上向流运行方式修复北方景观水体。分别进行静态实验及不同循环速率下的动态实验，考察对水体污染物去除过程。结果表明，2种运行方式下对水体NH⁺₄-N去除率都在85%以上，其中以1 h为循环周期的运行方式去除率达97%，较静态提高12.8%；TN去除率最高为84%；TP去除不稳定，过程缓慢。煤渣层对NH⁺₄-N的去除效果差，硝化作用不彻底与反硝化作用的加强使下层出水NH⁺₄-N 、NO^-₂-N及NO^-₃-N浓度均高于上层。提高循环速率有利于对氮的去除。     

反渗透处理稀土氨氮废水试验研究

根据稀土冶炼厂排放的碳铵沉淀洗涤废水的水质情况，采用NH4Cl和 NaCl模拟废水进行了反渗透可行性对比实验。模拟实验发现，在相同条件下反渗透对NaCl 较NH₄Cl 有着更高的去除率，而NH₄Cl 相对NaCl则有着更高的产水速率。实际废水试验结果表明，在恒定操作压力范围内回收率为65%的条件下，NH₄Cl浓度为2.85 g/L的碳铵沉淀洗涤废水经反渗透处理其NH₄Cl去除率为77.3%，可作为氨氮废水的预处理。对该废水处理成本进行了分析，得出其约为2.7元/m³，比相近浓度氨氮废水的氨吹脱处理成本节省约26%。     

钛基IrO2-SnO2电极在烟气海水脱硫恢复系统中的应用

采用浸渍-热分解法制备了含IrOx-TiO2中间层的IrO2-SnO2电极,得到的电极具有较高的析氯电催化活性和较强的稳定性,并通过电化学氧化法对Na2SO3海水脱硫模拟液进行处理,考察了电流密度、温度、pH值和电解时间等电解工艺参数对Na2SO3去除率和化学需氧量COD的影响.结果表明,在电流密度为200 mA/cm...     

容积负荷对ABR-MBR工艺反硝化除磷性能的影响

采用连续流ABR-MBR组合工艺处理生活污水,研究不同容积负荷(volume loading rate,VLR)对该工艺反硝化除磷性能的影响,获得最佳工艺参数.试验考察ABR进水容积负荷(以COD计,下同)分别为0.76、1.01、1.51和2.27 kg·(m~3·d)~(-1)时系统去碳脱氮除磷的性能,并在各ABR容积负荷条件下考察MBR容积负荷对MBR反应器硝化性能的影响.结果表明,在ABR进水容积负荷为1.51 kg·(m~3·d)~(-1)的条件下,系统A2隔室COD去除量最大,并在MBR容积负荷为0.462 kg·(m~3·d)~(-1)时,MBR反应器中实现了短程硝化,系统NH_4~+-N和TN去除率分别达到90%和72%以上,厌氧释磷量为7.41 mg·L~(-1),缺氧吸磷量达到15.42 mg·L~(-1),出水PO_4~(3-)-P浓度低于0.5 mg·L~(-1),这表明短程硝化更有利于强化ABR-MBR系统的反硝化除磷性能.     

常规施肥条件下农田不同途径氮素损失的原位研究:以长江中下游地区夏玉米季为例

为了解农田常规施肥条件下的不同途径氮素损失特征,本文通过田间原位试验同步研究了长江中下游地区夏玉米生长季氮肥施用后的农田N2O排放、NH3挥发、氮渗漏和地表径流的变化.结果表明,在复合肥为基肥,尿素为追肥,基追肥氮素水平均为150 kg·hm-2的条件下,整个玉米生长季N2O排放系数为3.3%,NH3挥发损失率为10.2%,氮渗漏和地表径流损失率分别为11.2%和5.1%.此外,基肥施用以氮素渗漏损失为主,而追肥氮素损失以氨挥发和渗漏为主,表明不同途径化肥氮素损失主要受氮肥品种影响,玉米季追肥可改用低氨挥发氮肥品种以减少氮素损失.